2001
c) You needed
to answer this Q. You should have described the effect of increasing C% but
also said why Mn, Si & Cu are added to steel in small amounts. You should
have detailed what the Cr, Ni and Mo are for in stainless steel and what the Ti
(and Nb…etc) are used for in HSLA steel. Tis would be a very good Q to
practise.
2003
aii) You must
note the properties of the passivating layer on passivating metals. For active
metals you must say that they react with air/water to corrode but their
corrosion product is often porous and non-tightly bound (eg rust) = NO BARRIER to further corrosion.
2005
bii) You
would get metal displacement between Mg and Fe ions – detail reactions &
explain why in terms of defining metal displacement and relating to Fe and Mg
reactivity. Also – you would get rusting of the nail – there is no electrical
contact between the Mg and Fe so no galvanic (sacrificial anode) cell can form
– thus detail the rusting equations. This is a question to redo!
2008
b) If you
start describing an experiment we didn’t do you risk accidentally missing
something that a student who DID the experiment you described would not =
putting you at a disadvantage. We put iron and stainless steel in test tubes of
equal conc salt water, same temp, pressure …. We weighed before and after 20
days. Visually observed (first appearance of rust and final extent of rust –
qualitative comparison) and weighed mass of samples once corrosion had been
wiped off. Stainless = no corrosion or mass loss. Iron – lots of orange/brown
corrosion and small mass loss. Was it reliable – NO – but you can still
demonstrate your understanding of reliability by noting that and defining
reliability OR you can say these values were compared to the results of the
previous year of HSC Chemistry classes and were found to be consist.
2010
c) There
was bit of a fuss that year because
despite the fact that the Q says they are steels, #3 is clearly cast iron. You
should pick up on this (ie anything > 2.1wt%C is no longer steel) and
specify its uses in gates/cookware/hotplates etc – hard strong good heat
retention. You need to explain what happens to the properties of steel when C
is increases (ie compare properties and applications of #1 and #2 – NB you
should explain why corrosion rates increase in terms of cathode sites). For
Steel #4 you need to explain what both the Cr and the Ni do.
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